Directed Vapor Technologies International, Inc. — Department of Defense STTR Phase II: ABSTRACT: Lightweight silicon-based ceramics are leading candidates to replace heavier ni

Description

ABSTRACT: Lightweight silicon-based ceramics are leading candidates to replace heavier nickel-based superalloys for use on hot section components in next generation gas turbine engines having increased specific power. However, exposures of these materials to the high temperatures, pressures and velocities of water vapor containing combustion environments alter the effectiveness of thermally grown silica scales in protecting the ceramic components from oxidation and component recession during service. Environmental barrier coatings(EBCs) are therefore required that protect the underlying ceramic substrate from environmental attack. Such coatings require good stability in the presence of water vapor, a mechanism for limiting the transport of oxygen and water vapor, good chemical compatibility at the interface of unlike materials, high temperature phase stability to limit volume changes resulting from phase transformations in the coating materials and the ability to provide thermal and erosion protection. The ongoing drive to promote higher temperature protection and prime reliant performance of these systems has led to interest in advanced thermal/environmental barrier coating(T/EBC) systems having enhanced performance over current state-of-the-art T/EBC systems. In this work, novel coating synthesis techniques that enable the deposition of multilayered T/EBC"s anticipated to have higher temperature capability and improved durability over of current systems are investigated. BENEFIT: This research is anticipated to result in a thermal/environmental barrier coating system that provides higher temperature capability, improved durability and better erosion resistance than current coatings. These advancements will enable the use of Si-based ceramics in a range of high temperature applications such a gas turbine engines and heat exchangers. These advances will not only benefit military engines, but also commercial and industrial engines requiring greater performance.